|
|
p-hydroxyphenylacetaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1-aci-nitro-2-(4-hydroxyphenyl)-ethane + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18756
|
|
|
|
N-hydroxy-L-tyrosine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N,N-dihydroxy-L-tyrosine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-7748
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-2-(4-hydroxyphenyl)ethan-1-imine + H2O <=> p-Hydroxyphenylacetothiohydroximate + L-seryl-glycine + H+
|
4.4.1.M2
|
–
|
| |
MetaCyc:
RXN-18760
|
|
|
|
N,N-dihydroxy-L-tyrosine + H+ <=> p-hydroxyphenylacetaldoxime + CO2 + H2O
|
1.14.14.36
tyrosine N-monooxygenase
|
–
|
| |
BRENDA:
BR47357
KEGG:
R07190
MetaCyc:
RXN-7749
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-2-(4-hydroxyphenyl)ethan-1-imine + H2O <=> S-(Hydroxyphenylacetothiohydroximoyl)-L-cysteine + glycine
|
3.4.13.23
cysteinylglycine-S-conjugate dipeptidase
|
–
|
| |
MetaCyc:
RXN-19595
|
|
|
|
UDP-glucose + p-Hydroxyphenylacetothiohydroximate <=> desulfo-p-hydroxy-benzylglucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
KEGG:
R08661
MetaCyc:
RXN-18761
|
|
|
|
S-(Hydroxyphenylacetothiohydroximoyl)-L-cysteine + H2O <=> p-Hydroxyphenylacetothiohydroximate + pyruvate + NH3 + H+
|
4.4.1
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
–
|
| |
KEGG:
R08660
MetaCyc:
RXN-19596
|
|
|
|
S-[(Z)-N-hydroxy(p-hydroxyphenyl)acetimidoyl]-L-glutathione + H2O <=> (E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-2-(4-hydroxyphenyl)ethan-1-imine + L-glutamate
|
3.4.19.16
glucosinolate gamma-glutamyl hydrolase
|
–
|
| |
MetaCyc:
RXN-18759
|
|
|
|
1-aci-nitro-2-(4-hydroxyphenyl)-ethane + glutathione <=> S-[(Z)-N-hydroxy(p-hydroxyphenyl)acetimidoyl]-L-glutathione + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18757
|
|
|
|
L-tyrosine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N-hydroxy-L-tyrosine + H2O + oxidized_[NADPH-hemoprotein_reductase] + H+
|
not assigned
|
–
|
| |
MetaCyc:
TYROSINE-N-MONOOXYGENASE-RXN
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-p-hydroxy-benzylglucosinolate <=> adenosine_3,5''-bisphosphate + p-hydroxybenzylglucosinolate + H+
|
2.8.2
2.8.2.24
aromatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
BRENDA:
BS358759
KEGG:
R08662
MetaCyc:
RXN-18762
|
|
